Calorie (th) to Therm (EC)

The thermochemical calorie (cal th) is defined as exactly 4.184 joules; the International Table calorie (cal IT) is exactly 4.1868 joules — a difference of 0.066%. The thermochemical value was fixed by the US National Bureau of Standards in 1935 for chemistry; the IT value was adopted for steam tables. In nutritional contexts, the difference is irrelevant, but in precise calorimetry it can matter.

Decades of published thermochemical data — heats of formation, bond energies, combustion enthalpies — are recorded in cal th and kcal th. Converting every reference table to joules would be error-prone and disruptive. Biochemistry textbooks still quote ATP hydrolysis at ~7.3 kcal/mol and glucose oxidation at ~686 kcal/mol. The convention persists because the existing literature is too vast to rewrite.

A dried, weighed food sample is sealed in a steel vessel filled with pure oxygen, submerged in a known mass of water. An electric spark ignites the sample, which burns completely. The temperature rise of the surrounding water — measured to 0.001°C — gives the total heat released. One degree rise per gram of water equals one calorie. Corrections for the heat capacity of the bomb itself, the ignition wire, and acid formation give results accurate to ±0.1%. Atwater then applied digestibility factors to convert bomb values to usable food energy.

Hydrogen releases about 34,000 cal th per gram; methane about 13,300 cal th/g; ethanol about 7,100 cal th/g; and glucose about 3,720 cal th/g. These values appear throughout chemistry textbooks as standard reference data. The higher the cal/g value, the more energy-dense the fuel — which is why hydrogen is attractive despite being hard to store.

Before 1935, the calorie was defined by water's heat capacity, which varies with temperature — the 15°C calorie, 20°C calorie, and mean calorie all differed slightly. The US National Bureau of Standards ended the ambiguity by defining the thermochemical calorie as exactly 4.184 J, a round value close to all the experimental variants. This gave chemists a fixed, reproducible conversion factor independent of water's quirky temperature-dependent heat capacity.

The EC therm is defined as exactly 105,505,600 joules; the US therm is 105,480,400 joules — a difference of 25,200 J (about 0.024%). The discrepancy arose from slightly different historical BTU definitions. For residential gas billing the difference is negligible, but in large-scale energy trading involving millions of therms, the distinction can affect settlement amounts.

The UK Gas Act 1995 mandated a switch from therms to kWh as part of broader metrication. One therm (EC) equals 29.3071 kWh. The change aligned gas billing with electricity billing, making it easier for consumers to compare energy costs. Older UK customers and industry veterans still refer to therms colloquially, and wholesale gas markets continued using therms for years after the retail switch.

A typical UK home uses 500–800 therms (EC) per year for heating and hot water, equivalent to roughly 14,700–23,400 kWh. Well-insulated newer homes may use under 400 therms, while large Victorian houses with poor insulation can exceed 1,200 therms. Ofgem's energy price cap is set in pence per kWh, but converting back to therms gives about £2.50–£3.50 per therm at recent rates.

One cubic meter of UK pipeline-quality natural gas contains roughly 38.5–39.5 MJ, which is about 0.365–0.374 therms (EC). Gas meters measure volume in cubic meters, and the utility applies a calorific value correction to convert to kWh (or therms). The correction factor varies by region and season because gas composition changes depending on the source field.

The therm (EC) was once the standard trading unit on the UK's NBP (National Balancing Point) gas market. In 2020, the ICE exchange switched NBP contracts from pence per therm to pence per kWh. Continental European hubs like TTF have always traded in euros per MWh. The therm is fading from professional use but remains in legacy contracts and older billing systems.