Electron Volt to Kilocalorie (th)

Because subatomic energies in joules have absurdly small exponents — a visible-light photon carries about 3 × 10⁻¹⁹ J, but a convenient 1.9 eV. The electron volt is scaled to the quantum world, making numbers human-readable. It also doubles as a mass unit (via E = mc²): a proton is 938.3 MeV/c², far easier to work with than 1.673 × 10⁻²⁷ kg.

Visible light photons range from about 1.65 eV (deep red, 750 nm) to 3.1 eV (violet, 400 nm). Green light, where the human eye is most sensitive, sits around 2.3 eV. Ultraviolet photons start at 3.1 eV and can exceed 100 eV in the extreme UV. These energies are why UV can damage DNA (breaking molecular bonds of 3–5 eV) while visible light cannot.

A semiconductor's bandgap — the minimum energy to free an electron from its bond — is expressed in eV. Silicon has a bandgap of 1.12 eV, gallium arsenide 1.42 eV, and gallium nitride 3.4 eV. The bandgap determines which wavelengths of light a solar cell can absorb and what color an LED emits. Lower bandgap means longer-wavelength (redder) light.

The LHC accelerates protons to 6.5 TeV (6.5 × 10¹² eV) per beam, giving collisions a center-of-mass energy of 13 TeV. That sounds enormous, but 13 TeV is only about 2 microjoules — the kinetic energy of a flying mosquito. The power of the LHC lies in concentrating that energy into a space a million times smaller than an atom.

Multiply by 1.602 176 634 × 10⁻¹⁹. So 1 eV = 1.602 × 10⁻¹⁹ J, 1 keV = 1.602 × 10⁻¹⁶ J, and 1 MeV = 1.602 × 10⁻¹³ J. This conversion factor is exactly the elementary charge in coulombs, because an electron volt is defined as the energy gained by one electron charge crossing one volt of potential.

Most foundational biochemical data — ATP hydrolysis (~7.3 kcal/mol), glucose oxidation (~686 kcal/mol), amino acid combustion values — were measured and published in kcal th before SI adoption. Rewriting decades of literature, lecture notes, and exam banks to kJ would introduce conversion errors and confusion. The field maintains kcal th by convention while acknowledging SI equivalents.

The standard free energy change (ΔG°) for ATP → ADP + Pi is approximately −7.3 kcal th/mol (−30.5 kJ/mol). Under actual cellular conditions, the value is closer to −12 to −14 kcal/mol because reactant and product concentrations differ from standard state. This energy drives muscle contraction, nerve impulses, protein synthesis, and virtually every energy-requiring process in living cells.

The classic Atwater factors (4 kcal/g carb, 4 kcal/g protein, 9 kcal/g fat) are averages from 19th-century bomb calorimetry, adjusted for digestibility. They can be off by 5–25% for specific foods. Almonds deliver ~20% fewer usable calories than labels claim because cell walls trap some fat from digestion. High-fiber foods also overcount. The FDA allows ±20% tolerance on label accuracy, so a "200 kcal" bar could legally contain 160–240 kcal.

Complete aerobic oxidation of one mole of glucose (C₆H₁₂O₆) releases approximately 686 kcal th (2,870 kJ). The human body captures about 38–40% of this in ATP; the rest dissipates as body heat. This is why exercise makes you warm — over half the food energy your muscles consume is released as thermal energy rather than mechanical work.

Fat molecules are highly reduced — their carbon atoms are bonded mostly to hydrogen, with very little oxygen. Oxidising them releases maximum energy because every C-H bond is converted to C=O and O-H bonds. Carbohydrates are already partially oxidised (they contain oxygen in their structure), so less additional oxidation is possible. Gram for gram, fat stores 2.25× more energy, which is why evolution favored fat as the body's long-term energy reserve — it packs the most kcal per gram of tissue weight.