Kilocalorie (th) to Therm (EC)

Most foundational biochemical data — ATP hydrolysis (~7.3 kcal/mol), glucose oxidation (~686 kcal/mol), amino acid combustion values — were measured and published in kcal th before SI adoption. Rewriting decades of literature, lecture notes, and exam banks to kJ would introduce conversion errors and confusion. The field maintains kcal th by convention while acknowledging SI equivalents.

The standard free energy change (ΔG°) for ATP → ADP + Pi is approximately −7.3 kcal th/mol (−30.5 kJ/mol). Under actual cellular conditions, the value is closer to −12 to −14 kcal/mol because reactant and product concentrations differ from standard state. This energy drives muscle contraction, nerve impulses, protein synthesis, and virtually every energy-requiring process in living cells.

The classic Atwater factors (4 kcal/g carb, 4 kcal/g protein, 9 kcal/g fat) are averages from 19th-century bomb calorimetry, adjusted for digestibility. They can be off by 5–25% for specific foods. Almonds deliver ~20% fewer usable calories than labels claim because cell walls trap some fat from digestion. High-fiber foods also overcount. The FDA allows ±20% tolerance on label accuracy, so a "200 kcal" bar could legally contain 160–240 kcal.

Complete aerobic oxidation of one mole of glucose (C₆H₁₂O₆) releases approximately 686 kcal th (2,870 kJ). The human body captures about 38–40% of this in ATP; the rest dissipates as body heat. This is why exercise makes you warm — over half the food energy your muscles consume is released as thermal energy rather than mechanical work.

Fat molecules are highly reduced — their carbon atoms are bonded mostly to hydrogen, with very little oxygen. Oxidising them releases maximum energy because every C-H bond is converted to C=O and O-H bonds. Carbohydrates are already partially oxidised (they contain oxygen in their structure), so less additional oxidation is possible. Gram for gram, fat stores 2.25× more energy, which is why evolution favored fat as the body's long-term energy reserve — it packs the most kcal per gram of tissue weight.

The EC therm is defined as exactly 105,505,600 joules; the US therm is 105,480,400 joules — a difference of 25,200 J (about 0.024%). The discrepancy arose from slightly different historical BTU definitions. For residential gas billing the difference is negligible, but in large-scale energy trading involving millions of therms, the distinction can affect settlement amounts.

The UK Gas Act 1995 mandated a switch from therms to kWh as part of broader metrication. One therm (EC) equals 29.3071 kWh. The change aligned gas billing with electricity billing, making it easier for consumers to compare energy costs. Older UK customers and industry veterans still refer to therms colloquially, and wholesale gas markets continued using therms for years after the retail switch.

A typical UK home uses 500–800 therms (EC) per year for heating and hot water, equivalent to roughly 14,700–23,400 kWh. Well-insulated newer homes may use under 400 therms, while large Victorian houses with poor insulation can exceed 1,200 therms. Ofgem's energy price cap is set in pence per kWh, but converting back to therms gives about £2.50–£3.50 per therm at recent rates.

One cubic meter of UK pipeline-quality natural gas contains roughly 38.5–39.5 MJ, which is about 0.365–0.374 therms (EC). Gas meters measure volume in cubic meters, and the utility applies a calorific value correction to convert to kWh (or therms). The correction factor varies by region and season because gas composition changes depending on the source field.

The therm (EC) was once the standard trading unit on the UK's NBP (National Balancing Point) gas market. In 2020, the ICE exchange switched NBP contracts from pence per therm to pence per kWh. Continental European hubs like TTF have always traded in euros per MWh. The therm is fading from professional use but remains in legacy contracts and older billing systems.