Therm (US) to Calorie (th)

Residential US natural gas prices typically range from $0.80 to $2.50 per therm depending on region, season, and utility. The wholesale Henry Hub benchmark translates to about $0.25 per therm at $2.50/MMBtu. Delivery charges, taxes, and utility markups roughly triple or quadruple the commodity cost by the time it reaches a home meter.

The average US home using gas for heating consumes about 500–900 therms per year, depending on climate, insulation, and home size. Homes in mild climates like Southern California may use under 300 therms; homes in Minnesota or Wisconsin can exceed 1,200 therms. Gas water heaters alone account for roughly 150–250 therms per year.

One US therm equals exactly 100,000 BTU, while one MMBtu (million BTU) equals 1,000,000 BTU — so 1 MMBtu equals 10 therms. Wholesale gas markets and pipeline contracts use MMBtu; residential utility bills use therms. The two are straightforward to convert, but confusing them by a factor of ten is a common mistake in energy cost comparisons.

Retail billing in therms gives homeowners manageable numbers — a winter month might be 80–120 therms at $1–2 each. Wholesale pipeline contracts deal in millions of BTU (MMBtu) because the volumes are enormous and the industry standardized on BTU-based pricing in the early 20th century. One MMBtu equals 10 therms, so converting is simple. The Henry Hub benchmark price of $2.50/MMBtu translates to about $0.25/therm before delivery charges, taxes, and utility markup roughly quadruple it at the meter.

A typical US residential furnace rated at 80,000–100,000 BTU/h uses about 0.8–1.0 therms per hour at full output. High-efficiency condensing furnaces (95%+ AFUE) extract more heat per therm, so they cycle less often. On a cold winter day, a furnace might run 8–12 hours total, consuming 6–10 therms. That translates to roughly $5–$25 per day depending on local gas prices.

The thermochemical calorie (cal th) is defined as exactly 4.184 joules; the International Table calorie (cal IT) is exactly 4.1868 joules — a difference of 0.066%. The thermochemical value was fixed by the US National Bureau of Standards in 1935 for chemistry; the IT value was adopted for steam tables. In nutritional contexts, the difference is irrelevant, but in precise calorimetry it can matter.

Decades of published thermochemical data — heats of formation, bond energies, combustion enthalpies — are recorded in cal th and kcal th. Converting every reference table to joules would be error-prone and disruptive. Biochemistry textbooks still quote ATP hydrolysis at ~7.3 kcal/mol and glucose oxidation at ~686 kcal/mol. The convention persists because the existing literature is too vast to rewrite.

A dried, weighed food sample is sealed in a steel vessel filled with pure oxygen, submerged in a known mass of water. An electric spark ignites the sample, which burns completely. The temperature rise of the surrounding water — measured to 0.001°C — gives the total heat released. One degree rise per gram of water equals one calorie. Corrections for the heat capacity of the bomb itself, the ignition wire, and acid formation give results accurate to ±0.1%. Atwater then applied digestibility factors to convert bomb values to usable food energy.

Hydrogen releases about 34,000 cal th per gram; methane about 13,300 cal th/g; ethanol about 7,100 cal th/g; and glucose about 3,720 cal th/g. These values appear throughout chemistry textbooks as standard reference data. The higher the cal/g value, the more energy-dense the fuel — which is why hydrogen is attractive despite being hard to store.

Before 1935, the calorie was defined by water's heat capacity, which varies with temperature — the 15°C calorie, 20°C calorie, and mean calorie all differed slightly. The US National Bureau of Standards ended the ambiguity by defining the thermochemical calorie as exactly 4.184 J, a round value close to all the experimental variants. This gave chemists a fixed, reproducible conversion factor independent of water's quirky temperature-dependent heat capacity.